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Old 2 Aug 2009, 11:39 AM   #1 (permalink)
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Extraction of zinc from sulfide ores

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Hey,

i was wondering if anyone knew the chemical equation for the processes involved in the extraction of zinc from sulfide ores. The processes that i have are:
-zinc is extracted from sulfide ores by roasting the ore forming an oxide
-the oxide is then dissolved in sulfuric acid
-the metal is obtained by electrolysis

thanks, any help is greatly appreciated
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Old 3 Oct 2009, 12:11 PM   #2 (permalink)
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Re: Extraction of zinc from sulfide ores

ZnS + O2 = Zn + SO2
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Old 7 Oct 2009, 8:51 PM   #3 (permalink)
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Re: Extraction of zinc from sulfide ores

Quote:
Originally Posted by charlen View Post
ZnS + O2 = Zn + SO2
zinc oxide matey.

and then dont forget to balance as well, after changed the mistake.

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Old 7 Oct 2009, 9:40 PM   #4 (permalink)
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Re: Extraction of zinc from sulfide ores

Quote:
Originally Posted by steve001 View Post
-zinc is extracted from sulfide ores by roasting the ore forming an oxide
ZnS + 3/2 O2 --> ZnO + SO2

Quote:
Originally Posted by steve001 View Post
-the oxide is then dissolved in sulfuric acid
ZnO + H2SO4 --> ZnSO4 + H2O

Quote:
Originally Posted by steve001 View Post
-the metal is obtained by electrolysis
Zn2+ + 2 e- --> Zn

---

There are two other processes:

ZnS + 3/2 O2 --> ZnO + SO2
SO2 + 1/2 O2 --> SO3
ZnO + SO3 --> ZnSO4
Zn2+ + 2 e- --> Zn

The reduction of zinc oxide occurs in excess of 1000o C, well above the boiling point of zinc metal. Zinc is formed as a gas and purified by distillation.
ZnS + 3/2 O2 --> ZnO + SO2
ZnO + C --> Zn + CO
ZnO + CO --> Zn + CO2
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