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Old 26 Sep 2009, 10:24 PM   #1 (permalink)
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How does an acidic environment accelerate corrosion???

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So confused! Different books give different reasons and different equations to support as well.

Also, what are some other methods of cleaning/stabilising artefacts other than electrolysis and removing concretions?

Thanks
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Old 26 Sep 2009, 10:30 PM   #2 (permalink)
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Re: How does an acidic environment accelerate corrosion???

Acidic environment accelerate rusting because of the following equilibrium reaction:
Fe (s) + 2H+ (aq) <--> Fe2+(aq) + H2 (g)
Applying Le Chatelier’s principle, an increase in acidity, which is H+ ions, would cause the equilibrium to shift to the right. This would lead to a faster corrosion of the iron.

But i too have seen diffferent ways of it being explained, i guess you should just stick to wha you're most comfortable with

Leeching can be used to clean/stabilise artefacts. It takes a long time to work though.
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Old 27 Sep 2009, 9:34 AM   #3 (permalink)
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Re: How does an acidic environment accelerate corrosion???

That helps a lot, thank you!
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Old 27 Sep 2009, 9:40 AM   #4 (permalink)
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Re: How does an acidic environment accelerate corrosion???

Glad i helped
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