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| | #16 (permalink) |
| Member | You can hide this advertisement by registering. Its not all art, in fact only one section is on art itself and that in itself isn't really on art. believe me when i say that because i did art for four years, however there is alot on colours. pretty colours and how they come about!! |
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| | #17 (permalink) | |
| Member HSC: 2004 Gender: Male
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2 Aug 2008, 3:12 PM ![]() | Quote:
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| | #18 (permalink) |
| Supreme Member HSC: 2004 Gender: Male Location: my house
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4 Nov 2009, 5:16 PM ![]() ![]() | To cameron0110: This site has a few links.. only a few though ![]() http://science.uniserve.edu.au/schoo...m/chemart.html >> It basically means that I need a copy of the syllabus nearby << It's not that much trouble |
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| | #19 (permalink) |
| Member HSC: 2004 Gender: Male
Join Date: Mar 2004
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2 Aug 2008, 3:12 PM ![]() | I know its not that much trouble, I just like being lazy and complaining when I can't be. In actual fact a lot of this topic isn't too hard based on the fact that its almost all Monitoring and Management stuff so its almost like doing extended revision. So far so good, hopefully the sodium doublet stuff is the hardest this gets, although i doubt it- but at least i get that stuff which is a start. |
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| | #21 (permalink) |
| Member HSC: 2004 Gender: Male
Join Date: Mar 2004
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2 Aug 2008, 3:12 PM ![]() | Ok here is my take on the whole issue. Bohr's assumptions were that the subshells at one distinct energy level all contained the same energy. i.e. 2s was the same energy as 2p, which it was for Hydrogen however this didn't work for other elements because of Schroedinger's uncertainty principle which stated that we can't identify where an electron is, we can only work out the probability of it being in a certain location. The 2s shell has a small probability of being in close to the nucleus while the 2p doesn't really have the same level of probability which means that the 2s shell partially shields the 2p shell from nuclear charge. This means that 2s is held closer to the nucleus while 2p is further out meaning they possess different energy levels. Due to the magnetic field possessed by electrons caused by their rotations and spin, the 2p subshell in Sodium splits with 2 orbitals being at one energy level and 1 at a slightly different energy level. The energy released from 2p to 2s in sodium is at a yellow wavelength and the subtle energy difference results in the doublet as there is only a very small difference in energies so they have similar wavelengths leading to the creation of the Sodium doublet. I'm sorry about any innaccuracies in that and if anyone knows better than can correct me cause that was just off the top of my head so I've probably got something wrong. |
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| | #22 (permalink) |
| Member HSC: 2004 Gender: Male
Join Date: Mar 2004
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2 Aug 2008, 3:12 PM ![]() | Ok here is my take on the whole issue. Bohr's assumptions were that the subshells at one distinct energy level all contained the same energy. i.e. 2s was the same energy as 2p, which it was for Hydrogen however this didn't work for other elements because of Schroedinger's uncertainty principle which stated that we can't identify where an electron is, we can only work out the probability of it being in a certain location. The 2s shell has a small probability of being in close to the nucleus while the 2p doesn't really have the same level of probability which means that the 2s shell partially shields the 2p shell from nuclear charge. This means that 2s is held closer to the nucleus while 2p is further out meaning they possess different energy levels. Due to the magnetic field possessed by electrons caused by their rotations and spin, the 2p subshell in Sodium splits with 2 orbitals being at one energy level and 1 at a slightly different energy level. The energy released from 2p to 2s in sodium is at a yellow wavelength and the subtle energy difference results in the doublet as there is only a very small difference in energies so they have similar wavelengths leading to the creation of the Sodium doublet. I'm sorry about any innaccuracies in that and if anyone knows better than can correct me cause that was just off the top of my head so I've probably got something wrong. |
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| | #23 (permalink) |
| Member HSC: 2004 Gender: Male
Join Date: Mar 2004
Posts: 114
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2 Aug 2008, 3:12 PM ![]() | Ok here is my take on the whole issue. Bohr's assumptions were that the subshells at one distinct energy level all contained the same energy. i.e. 2s was the same energy as 2p, which it was for Hydrogen however this didn't work for other elements because of Schroedinger's uncertainty principle which stated that we can't identify where an electron is, we can only work out the probability of it being in a certain location. The 2s shell has a small probability of being in close to the nucleus while the 2p doesn't really have the same level of probability which means that the 2s shell partially shields the 2p shell from nuclear charge. This means that 2s is held closer to the nucleus while 2p is further out meaning they possess different energy levels. Due to the magnetic field possessed by electrons caused by their rotations and spin, the 2p subshell in Sodium splits with 2 orbitals being at one energy level and 1 at a slightly different energy level. The energy released from 2p to 2s in sodium is at a yellow wavelength and the subtle energy difference results in the doublet as there is only a very small difference in energies so they have similar wavelengths leading to the creation of the Sodium doublet. I'm sorry about any innaccuracies in that and if anyone knows better than can correct me cause that was just off the top of my head so I've probably got something wrong. |
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