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Old 3 Jul 2009, 5:35 PM   #5 (permalink)
jetblack2007
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Re: Melting/Boiling points

The way I understand it, the larger the molecule, the more electrons that are displaced to create the temporary dipole and hence the greater the force between molecules.

In order for a substance to melt and then boil, intermolecular forces must be overcome. Thus, the stronger the intermolecular forces, the higher the melting/boiling points.

Consequently, the larger the molecule, the higher the melting and boiling points of that substance.
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