Starting with the acceleration equation:
It is given that the maximum acceleration is
, and from the equation we can see that the maximum acceleration occurs when
is lowest.
i.e.
Substituting in, we get
.
(This is only valid if we assume that the origin is the centre of motion, but this assumption can be made "without loss of generality" since the velocity and acceleration of an object under SHM are not dependent on its original position)
Then moving to the velocity equation:
It is given that
.
From the equation it is clear that
is at a maximum when
.
i.e.
Therefore
, since
and
must both be positive.
Taking the two equations
and solving gives
.
For your second question the answer is yes.