na/nb = sin @a / sin @b is applicable to all monochormatic rays, regardless of whether the initial medium is air/vaccuum...
the refractive index n = c/v.... which means how slow the em wave propagate with repective to its velocity in vacuum... hence, the greater the n, the slower the em wave will travel....
hence, na/nb is teh ratio of velocity of waves enterin from one medium to a second medium with respect to the velocity of light invaccuum... that ratio is not affected by which medium u started with initially, and which one u ended up with...