Well, the location of 3/z on the Argand Diagram doesn't really matter, since a triangle will be formed with z, 3/z and the origin, regardless of where, z or 3/z are.
But if you really want to know, I'm not sure if my way of thinking is correct, but if you let z = x+iy and realise 3/z, you end up with 3x/(x^2 + y^2) - i (3y/(x^2 + y^2)).
So i guess, 3/z will always be on the same side of the y-axis with z, i.e. if Re(z) is greater than zero, then Re(3/z) is also greater than zero.(z and 3/z are right of the y-axis)
Whereas, 3/z will always be on the opposite side of the x-axis with z i.e. if Im(z) is greater than zero, then Im(3/z) is less than zero. (z is over the x-axis and 3/z is under the x-axis) (because of the minus)