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fullonoob

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A catalyst (conc. H2SO4) is essential to allow the rxn to take place at low temps. Why low temps?
 

fullonoob

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thx and what is the diff between equivalence point and end point.
 

js992

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The end point is the point at which there is a permanent colour change in the indicator.

The equivalence point is where the exact amount of titrant has been added to your aliquot to completely neutralise each other.
 

fullonoob

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The end point is the point at which there is a permanent colour change in the indicator.

The equivalence point is where the exact amount of titrant has been added to your aliquot to completely neutralise each other.
so end point = change in colour?
equivalence point = neutral substance? (isn't that change in colour as well)

My teacher said equivalence point = theoretical and end point = experimental. Is this true?
 

mtsmahia

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so end point = change in colour?
equivalence point = neutral substance? (isn't that change in colour as well)

My teacher said equivalence point = theoretical and end point = experimental. Is this true?
yes ur teacher is right..

The end point is in regards to the experimental evidence & Equivalence point refers to ur calculations (theory).
They are different because, end point depends on what u perceive to be as a colour change, and it may not correspond to the num of moles added from burete to neutralize the unknown solution. So in reality they wont be the same value :D
 

js992

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Your end point will depend on what indicator you choose and will certainly not always reflect your equivalence point all the time.
Eg. When a strong base is neutralised with strong base, the salt produced is neutral hence has a pH of 7. The equivalence point is therefore at about a pH of 7.

Choosing phenophthaelein as your indicator will give you an end point of pH approximately ~9. Hence it is not at the equivalence point

However if you choose bromothymol blue which changes colour from 6.0-7.6, the end point will be quite close to your equivalences point.

And also, when two substances neutralise, they dont necessarily form a neutral salt.
 

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