doesnt 1,2-dichloroprop-1-ene fit cause you could assume Q might have a double bond and since doesnt specify excess cl2 it could only have 1 double bond being saturated also 1,2-dichloroprop-1-ene has 32 percent carbon by mass and has molecular ion peak at 114 it also has a fragment at 15 and 62?
No, it doesn't. 1,2-dichloroprop-1-ene could not be made by addition to an alkene.
Starting with propadiene (CH
2=C=CH
2) would yield 2,3-dichloroprop-1-ene assuming reaction with one equivalent (assuming that dienes like this react in this way), rather than to yield 1,2-dichloroprop-1-ene.
Starting with propyne (CH
3-CCH) would yield an addition product of 1,2-dichloroprop-1-ene from 1 equivalent, but the question specified that the starting material was an alkene, Q, so Q can't be propyne.
Further, if the product was 1,2-dichloroprop-1-ene, ClCH=CCl-CH
3, its parent ions would be:
- C3H435Cl2+ . at m/z = 3 x 12 + 4 + 35 x 2 = 110
- C3H435Cl137Cl1+ . at m/z = 3 x 12 + 4 + 35 + 37 = 112
- C3H437Cl2+ . at m/z = 3 x 12 + 4 + 37 x 2 = 114
with relative intensities 9 : 6 : 1, yet the mass spectrum provided clearly shows the largest intensity molecular ion is at 112.