The question is that why is the moles in 250mL the same in 75mL. Shouldn't the moles change after you go to the 75ml bottle?
All of the citric acid in the experiment system was originally contained in the 75mL of bottled drink.
Water was added to make the solution a total volume of 250mL - in other words,
the citric acid concentration became more dilute in the titration solution compared to the drink but the total amount of it hadn't changed, between the drink and the solution.
The second titration only used 25mL of the diluted solution (ie. one tenth of the 250mL volume), so the amount that was determined, by titration, to be in 25mL (0.00097331791), had to be multiplied by ten to get the total amount in the 250mL solution which was all the citric acid in the original drink bottle of 75mL, so to determine the
concentration in the
original drink, the total
amount in the solution should be divided by the
original volume of the bottled drink.