titration calculations (1 Viewer)

persephone

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when we did titration my teacher was pretty relaxed but what were we supposed to do with out results? you know after the phenolphthalein changed colour. etc

we write a balanced equation, thn we figure out the moles of acid then calculate moles of base and then what?
 

helper

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Calculate the concentration of your unknown solution
 

smallcattle

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then you divide the moles by the volumn of the base used to get the concentration
 

mercury

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Purpose of Titration

What you are doing in a titration is you are trying to determine the concentration of an unknown acid (or base) using a base (or acid) of known concentration. A simple example would be like this:

suppose you have NaOH of 0.1000 M concentration (this is your standard, ie. solution of known concentration). you have some HCl of not accurately known concentration (say about 0.1), and you need to find an accurate concentration for it (4 sig figs)

Then you take 25mL of acid and deliver into a conical flask using a pipette.
You fill up your burette with NaOH. Add 2/3 drops phenolthalein to your conical flask. Record your initial reading on burette. Add NaOH from the burette into the flask until the solution becomes very very faint pink that disappears after about 10 seconds. Record final reading on burette.

Usually you'd repeat this 3 or 4 times.

Sample Calculation


1) Initial Volume: 10.15 mL (you always take reading to 2 dp)
Final Volume: 32.55 mL

Volume of NaOH used = 32.55 - 10.15 = 22.40 mL

2) You would do this for ALL your replicates, and then average the volume of NaOH used. Suppose you got 22.35, 22. 60, 25.45, 22.40, you would discard 22.60 because it is too different to others (usually the values should be at least within 0.1 mL)

3) Suppose your average value is 22.25 mL. In this simple example, ratio of OH- to H+ is 1 to 1, therefore:
number of moles of NaOH consumed = number of moles of H+ in the conical flask

moles(NaOH) = 0.02240 x 0.1000 = moles(H+)
[H+] = moles(H+)/0.025



 

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